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In Situ Designing a Gradient Li + Capture and Quasi‐Spontaneous Diffusion Anode Protection Layer toward Long‐Life Li−O 2 Batteries
Author(s) -
Yu Yue,
Huang Gang,
Wang JiaZhi,
Li Kai,
Ma JinLing,
Zhang XinBo
Publication year - 2020
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.202004157
Subject(s) - materials science , anode , lithium (medication) , electrolyte , lithium fluoride , nucleation , chemical engineering , electrochemistry , layer (electronics) , dendrite (mathematics) , carbon fibers , passivation , electrode , inorganic chemistry , nanotechnology , composite material , chemistry , organic chemistry , composite number , medicine , geometry , mathematics , engineering , endocrinology
Lithium metal is the only anode material that can enable the Li−O 2 battery to realize its high theoretical energy density (≈3500 Wh kg −1 ). However, the inherent uncontrolled dendrite growth and serious corrosion limitations of lithium metal anodes make it experience fast degradation and impede the practical application of Li−O 2 batteries. Herein, a multifunctional complementary LiF/F‐doped carbon gradient protection layer on a lithium metal anode by one‐step in situ reaction of molten Li with poly(tetrafluoroethylene) (PTFE) is developed. The abundant strong polar C‐F bonds in the upper carbon can not only act as Li + capture site to pre‐uniform Li + flux but also regulate the electron configuration of LiF to make Li + quasi‐spontaneously diffuse from carbon to LiF surface, avoiding the strong Li + ‐adhesion‐induced Li aggregation. For LiF, it can behave as fast Li + conductor and homogenize the nucleation sites on lithium, as well as ensure firm connection with lithium. As a result, this well‐designed protection layer endows the Li metal anode with dendrite‐free plating/stripping and anticorrosion behavior both in ether‐based and carbonate ester‐based electrolytes. Even applied protected Li anodes in Li−O 2 batteries, its superiority can still be maintained, making the cell achieve stable cycling performance (180 cycles).