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Structural Approaches to Control Interlayer Interactions in 2D Covalent Organic Frameworks
Author(s) -
MartínezAbadía Marta,
MateoAlonso Aurelio
Publication year - 2020
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.202002366
Subject(s) - materials science , covalent bond , monomer , crystallinity , curse of dimensionality , chemical physics , nanotechnology , polymer , topology (electrical circuits) , organic chemistry , chemistry , computer science , composite material , mathematics , combinatorics , machine learning
The ability to design and synthesize monomers can affect fundamental aspects in 2D covalent organic frameworks, such as dimensionality, topology, and pore size. Besides this, the structure of the monomers can also affect interlayer interactions, which provide an additional means to influence crystallinity, layer arrangement, interlayer distances, and exfoliability. Herein, some of the effects that the structure of monomers can have on the interlayer interactions in 2D covalent organic frameworks and related materials are illustrated.