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Graphdiyne Derivative as Multifunctional Solid Additive in Binary Organic Solar Cells with 17.3% Efficiency and High Reproductivity
Author(s) -
Liu Le,
Kan Yuanyuan,
Gao Ke,
Wang Jianxiao,
Zhao Min,
Chen Hao,
Zhao Chengjie,
Jiu Tonggang,
Jen AlexK.Y.,
Li Yuliang
Publication year - 2020
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201907604
Subject(s) - materials science , organic solar cell , crystallinity , chemical engineering , photovoltaic system , nanotechnology , optoelectronics , polymer , composite material , ecology , engineering , biology
Morphology tuning of the blend film in organic solar cells (OSCs) is a key approach to improve device efficiencies. Among various strategies, solid additive is proposed as a simple and new way to enable morphology tuning. However, there exist few solid additives reported to meet such expectations. Herein, chlorine‐functionalized graphdiyne (GCl) is successfully applied as a multifunctional solid additive to fine‐tune the morphology and improve device efficiency as well as reproductivity for the first time. Compared with 15.6% efficiency for control devices, a record high efficiency of 17.3% with the certified one of 17.1% is obtained along with the simultaneous increase of short‐circuit current ( J sc ) and fill factor (FF), displaying the state‐of‐the‐art binary organic solar cells at present. The redshift of the film absorption, enhanced crystallinity, prominent phase separation, improved mobility, and decreased charge recombination synergistically account for the increase of J sc and FF after introducing GCl into the blend film. Moreover, the addition of GCl dramatically reduces batch‐to‐batch variations benefiting mass production owing to the nonvolatile property of GCl. All these results confirm the efficacy of GCl to enhance device performance, demonstrating a promising application of GCl as a multifunctional solid additive in the field of OSCs.