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Photonic Microcapsules Containing Single‐Crystal Colloidal Arrays with Optical Anisotropy
Author(s) -
Choi Tae Min,
Lee Gun Ho,
Kim YoungSeok,
Park JinGyu,
Hwang Hyerim,
Kim ShinHyun
Publication year - 2019
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201900693
Subject(s) - materials science , colloidal crystal , colloid , nucleation , crystallite , chemical physics , anisotropy , isotropy , crystallography , crystal (programming language) , single crystal , emulsion , crystal structure , nanotechnology , chemical engineering , optics , chemistry , physics , organic chemistry , computer science , engineering , metallurgy , programming language
Colloidal particles with a repulsive interparticle potential spontaneously form crystalline lattices, which are used as a motif for photonic materials. It is difficult to predict the crystal arrangement in spherical volume as lattices are incompatible with a spherical surface. Here, the optimum arrangement of charged colloids is experimentally investigated by encapsulating them in double‐emulsion drops. Under conditions of strong interparticle repulsion, the colloidal crystal rapidly grows from the surface toward the center of the microcapsule, forming an onion‐like arrangement. By contrast, for weak repulsion, crystallites slowly grow and fuse through rearrangement to form a single‐crystal phase. Single‐crystal structure is energetically favorable even for strong repulsion. Nevertheless, a high energy barrier to colloidal rearrangement kinetically arrests the onion‐like structure formed by heterogeneous nucleation. Unlike the isotropic onion‐shaped product, the anisotropic single‐crystal‐containing microcapsules selectively display—at certain orientations but not others—one of the distinct colors from the various crystal planes.