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Dual‐Programmable Shape‐Morphing and Self‐Healing Organohydrogels Through Orthogonal Supramolecular Heteronetworks
Author(s) -
Zhao Ziguang,
Zhuo Shuyun,
Fang Ruochen,
Zhang Longhao,
Zhou Xintao,
Xu Yichao,
Zhang Jianqi,
Dong Zhichao,
Jiang Lei,
Liu Mingjie
Publication year - 2018
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201804435
Subject(s) - morphing , materials science , supramolecular chemistry , dual (grammatical number) , nanotechnology , computer science , artificial intelligence , physics , art , literature , quantum mechanics , molecule
Programmable materials that can change their inherent shapes or properties are highly desirable due to their promising applications. However, among various programmable shape‐morphing materials, the single control route allows temporary states to recover the unchangeable former state, thus lacking the sophisticated programmability for their shape‐encoding behaviors and mechanics. Herein, dual‐programmable shape‐morphing organohydrogels featuring supramolecular heteronetworks are developed. In the system, the metallo‐supramolecular hydrogel framework and micro‐organogels featuring semicrystalline comb‐type networks independently respond to different stimuli, thereby providing orthogonal dual‐switching mechanics and ultrahigh mechanical strength. The supramolecular heteronetworks also possess excellent self‐healing properties. More notably, such orthogonal supramolecular heteronetworks demonstrate hierarchical shape morphing performance that far exceeds conventional shape‐morphing materials. Utilizing this dual programming strategy of the orthogonal supramolecular heteronetworks, the material's permanent shape can be manipulated in a step‐wise shape morphing process, thereby realizing sophisticated shape changes with a high degree of freedom. The organohydrogels can act as a biomimetic smart device for the on‐demand control of unidirectional liquid transport. Based on these characteristics, it is anticipated that the supramolecular organohydrogels may serve as adaptive programmable materials for a variety of applications.