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Superficial‐Layer‐Enhanced Raman Scattering (SLERS) for Depth Detection of Noncontact Molecules
Author(s) -
Qiao Xuezhi,
Xue Zhenjie,
Liu Lu,
Liu Keyan,
Wang Tie
Publication year - 2019
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201804275
Subject(s) - materials science , raman spectroscopy , raman scattering , noble metal , plasmon , penetration (warfare) , penetration depth , nanoparticle , surface enhanced raman spectroscopy , layer (electronics) , optics , optoelectronics , nanotechnology , metal , physics , operations research , metallurgy , engineering
Although the strength of Raman signals can be increased by many orders of magnitude on noble metal nanoparticles, this enhancement is confined to an extremely short distance from the Raman‐active surface. The key to the development of Raman spectroscopy for applications in diagnosis and detection of cancer and inflammatory diseases, and in pharmacology, relies on the capability of detecting analytes that are noninteractive with Raman‐active surfaces. Here, a new Raman enhancement system is constructed, superficial‐layer‐enhanced Raman scattering (SLERS), by covering elongated tetrahexahedral gold nanoparticle arrays with a superficial perovskite (CH 3 NH 3 PbBr 3 ) film. Plasmonic decay is depressed along the vertical direction away from the noble metal surface and the penetration depth is increased in the perovskite media. The vertical penetration of SLERS is verified by the spatial distribution of the analytes via Raman imaging in layer‐scanning mode.