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Hybridization of MOFs and COFs: A New Strategy for Construction of MOF@COF Core–Shell Hybrid Materials
Author(s) -
Peng Yongwu,
Zhao Meiting,
Chen Bo,
Zhang Zhicheng,
Huang Ying,
Dai Fangna,
Lai Zhuangchai,
Cui Xiaoya,
Tan Chaoliang,
Zhang Hua
Publication year - 2018
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201705454
Subject(s) - materials science , hybrid material , covalent organic framework , metal organic framework , nanotechnology , crystallinity , rhodamine b , photocatalysis , porous medium , covalent bond , porosity , catalysis , composite material , organic chemistry , chemistry , adsorption
The exploration of new porous hybrid materials is of great importance because of their unique properties and promising applications in separation of materials, catalysis, etc. Herein, for the first time, by integration of metal–organic frameworks (MOFs) and covalent organic frameworks (COFs), a new type of MOF@COF core–shell hybrid material, i.e., NH 2 ‐MIL‐68@TPA‐COF, with high crystallinity and hierarchical pore structure, is synthesized. As a proof‐of‐concept application, the obtained NH 2 ‐MIL‐68@TPA‐COF hybrid material is used as an effective visible‐light‐driven photocatalyst for the degradation of rhodamine B. The synthetic strategy in this study opens up a new avenue for the construction of other MOF–COF hybrid materials, which could have various promising applications.