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Roll‐to‐Roll Production of Transparent Silver‐Nanofiber‐Network Electrodes for Flexible Electrochromic Smart Windows
Author(s) -
Lin Sen,
Bai Xiaopeng,
Wang Haiyang,
Wang Haolun,
Song Jianan,
Huang Kai,
Wang Chang,
Wang Ning,
Li Bo,
Lei Ming,
Wu Hui
Publication year - 2017
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201703238
Subject(s) - materials science , electrochromism , electrode , roll to roll processing , indium tin oxide , electrochromic devices , tin oxide , transmittance , nanofiber , optoelectronics , sintering , continuous production , nanotechnology , composite material , doping , thin film , chemistry
Electrochromic smart windows (ECSWs) are considered as the most promising alternative to traditional dimming devices. However, the electrode technology in ECSWs remains stagnant, wherein inflexible indium tin oxide and fluorine‐doped tin oxide are the main materials being used. Although various complicated production methods, such as high‐temperature calcination and sputtering, have been reported, the mass production of flexible and transparent electrodes remains challenging. Here, a nonheated roll‐to‐roll process is developed for the continuous production of flexible, extralarge, and transparent silver nanofiber (AgNF) network electrodes. The optical and mechanical properties, as well as the electrical conductivity of these products (i.e., 12 Ω sq −1 at 95% transmittance) are comparable with those AgNF networks produced via high‐temperature sintering. Moreover, the as‐prepared AgNF network is successfully assembled into an A4‐sized ECSW with short switching time, good coloration efficiency, and flexibility.

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