Premium
Nanoscale Bubble Domains and Topological Transitions in Ultrathin Ferroelectric Films
Author(s) -
Zhang Qi,
Xie Lin,
Liu Guangqing,
Prokhorenko Sergei,
Nahas Yousra,
Pan Xiaoqing,
Bellaiche Laurent,
Gruverman Alexei,
Valanoor Nagarajan
Publication year - 2017
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201702375
Subject(s) - ferroelectricity , materials science , condensed matter physics , bubble , piezoresponse force microscopy , phase transition , polarization (electrochemistry) , topological defect , scanning tunneling microscope , dielectric , nanotechnology , optoelectronics , physics , chemistry , mechanics
Observation of a new type of nanoscale ferroelectric domains, termed as “bubble domains”—laterally confined spheroids of sub‐10 nm size with local dipoles self‐aligned in a direction opposite to the macroscopic polarization of a surrounding ferroelectric matrix—is reported. The bubble domains appear in ultrathin epitaxial PbZr 0.2 Ti 0.8 O 3 /SrTiO 3 /PbZr 0.2 Ti 0.8 O 3 ferroelectric sandwich structures due to the interplay between charge and lattice degrees of freedom. The existence of the bubble domains is revealed by high‐resolution piezoresponse force microscopy (PFM), and is corroborated by aberration‐corrected atomic‐resolution scanning transmission electron microscopy mapping of the polarization displacements. An incommensurate phase and symmetry breaking is found within these domains resulting in local polarization rotation and hence impart a mixed Néel–Bloch‐like character to the bubble domain walls. PFM hysteresis loops for the bubble domains reveal that they undergo an irreversible phase transition to cylindrical domains under the electric field, accompanied by a transient rise in the electromechanical response. The observations are in agreement with ab‐initio‐based calculations, which reveal a very narrow window of electrical and elastic parameters that allow the existence of bubble domains. The findings highlight the richness of polar topologies possible in ultrathin ferroelectric structures and bring forward the prospect of emergent functionalities due to topological transitions.