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Enhancing Performance of Nonfullerene Acceptors via Side‐Chain Conjugation Strategy
Author(s) -
Wang Jiayu,
Wang Wei,
Wang Xiaohui,
Wu Yang,
Zhang Qianqian,
Yan Cenqi,
Ma Wei,
You Wei,
Zhan Xiaowei
Publication year - 2017
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201702125
Subject(s) - homo/lumo , side chain , conjugated system , materials science , acceptor , absorption (acoustics) , organic solar cell , energy conversion efficiency , electron acceptor , photochemistry , electron mobility , absorption spectroscopy , molar absorptivity , polymer solar cell , chemistry , polymer , optoelectronics , molecule , physics , organic chemistry , optics , composite material , condensed matter physics
A side‐chain conjugation strategy in the design of nonfullerene electron acceptors is proposed, with the design and synthesis of a side‐chain‐conjugated acceptor (ITIC2) based on a 4,8‐bis(5‐(2‐ethylhexyl)thiophen‐2‐yl)benzo[1,2‐ b :4,5‐ b′ ]di(cyclopenta‐dithiophene) electron‐donating core and 1,1‐dicyanomethylene‐3‐indanone electron‐withdrawing end groups. ITIC2 with the conjugated side chains exhibits an absorption peak at 714 nm, which redshifts 12 nm relative to ITIC1. The absorption extinction coefficient of ITIC2 is 2.7 × 10 5 m −1 cm −1 , higher than that of ITIC1 (1.5 × 10 5 m −1 cm −1 ). ITIC2 exhibits slightly higher highest occupied molecular orbital (HOMO) (−5.43 eV) and lowest unoccupied molecular orbital (LUMO) (−3.80 eV) energy levels relative to ITIC1 (HOMO: −5.48 eV; LUMO: −3.84 eV), and higher electron mobility (1.3 × 10 −3 cm 2 V −1 s −1 ) than that of ITIC1 (9.6 × 10 −4 cm 2 V −1 s −1 ). The power conversion efficiency of ITIC2‐based organic solar cells is 11.0%, much higher than that of ITIC1‐based control devices (8.54%). Our results demonstrate that side‐chain conjugation can tune energy levels, enhance absorption, and electron mobility, and finally enhance photovoltaic performance of nonfullerene acceptors.