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Light‐Switchable Oxygen Vacancies in Ultrafine Bi 5 O 7 Br Nanotubes for Boosting Solar‐Driven Nitrogen Fixation in Pure Water
Author(s) -
Wang Shengyao,
Hai Xiao,
Ding Xing,
Chang Kun,
Xiang Yonggang,
Meng Xianguang,
Yang Zixin,
Chen Hao,
Ye Jinhua
Publication year - 2017
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201701774
Subject(s) - materials science , photocatalysis , bismuth , semiconductor , photochemistry , visible spectrum , nitrogen fixation , nanotechnology , oxygen , water splitting , catalysis , chemical engineering , nitrogen , optoelectronics , organic chemistry , chemistry , engineering , metallurgy
Solar‐driven reduction of dinitrogen (N 2 ) to ammonia (NH 3 ) is severely hampered by the kinetically complex and energetically challenging multielectron reaction. Oxygen vacancies (OVs) with abundant localized electrons on the surface of bismuth oxybromide‐based semiconductors are demonstrated to have the ability to capture and activate N 2 , providing an alternative pathway to overcome such limitations. However, bismuth oxybromide materials are susceptible to photocorrosion, and the surface OVs are easily oxidized and therefore lose their activities. For realistic photocatalytic N 2 fixation, fabricating and enhancing the stability of sustainable OVs on semiconductors is indispensable. This study shows the first synthesis of self‐assembled 5 nm diameter Bi 5 O 7 Br nanotubes with strong nanotube structure, suitable absorption edge, and many exposed surface sites, which are favorable for furnishing sufficient visible light‐induced OVs to realize excellent and stable photoreduction of atmospheric N 2 into NH 3 in pure water. The NH 3 generation rate is as high as 1.38 mmol h −1 g −1 , accompanied by an apparent quantum efficiency over 2.3% at 420 nm. The results presented herein provide new insights into rational design and engineering for the creation of highly active catalysts with light‐switchable OVs toward efficient, stable, and sustainable visible light N 2 fixation in mild conditions.