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Giant Ferroelectric Polarization in Ultrathin Ferroelectrics via Boundary‐Condition Engineering
Author(s) -
Xie Lin,
Li Linze,
Heikes Colin A.,
Zhang Yi,
Hong Zijian,
Gao Peng,
Nelson Christopher T.,
Xue Fei,
Kioupakis Emmanouil,
Chen Longqing,
Schlom Darrel G.,
Wang Peng,
Pan Xiaoqing
Publication year - 2017
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201701475
Subject(s) - materials science , ferroelectricity , polarization (electrochemistry) , scanning transmission electron microscopy , phase boundary , condensed matter physics , transmission electron microscopy , density functional theory , nanotechnology , phase (matter) , optoelectronics , dielectric , computational chemistry , chemistry , physics , organic chemistry
Tailoring and enhancing the functional properties of materials at reduced dimension is critical for continuous advancement of modern electronic devices. Here, the discovery of local surface induced giant spontaneous polarization in ultrathin BiFeO 3 ferroelectric films is reported. Using aberration‐corrected scanning transmission electron microscopy, it is found that the spontaneous polarization in a 2 nm‐thick ultrathin BiFeO 3 film is abnormally increased up to ≈90–100 µC cm −2 in the out‐of‐plane direction and a peculiar rumpled nanodomain structure with very large variation in c / a ratios, which is analogous to morphotropic phase boundaries (MPBs), is formed. By a combination of density functional theory and phase‐field calculations, it is shown that it is the unique single atomic Bi 2 O 3 − x layer at the surface that leads to the enhanced polarization and appearance of the MPB‐like nanodomain structure. This finding clearly demonstrates a novel route to the enhanced functional properties in the material system with reduced dimension via engineering the surface boundary conditions.