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Architecture of β‐Graphdiyne‐Containing Thin Film Using Modified Glaser–Hay Coupling Reaction for Enhanced Photocatalytic Property of TiO 2
Author(s) -
Li Jiaqiang,
Xie Ziqian,
Xiong Yan,
Li Zhenzhu,
Huang Qunxing,
Zhang Shuqing,
Zhou Jingyuan,
Liu Rong,
Gao Xin,
Chen Changguo,
Tong Lianming,
Zhang Jin,
Liu Zhongfan
Publication year - 2017
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201700421
Subject(s) - materials science , foil method , graphyne , photocatalysis , work function , band gap , thin film , coupling (piping) , conductivity , chemical engineering , nanocomposite , nanotechnology , composite material , optoelectronics , layer (electronics) , organic chemistry , chemistry , graphene , catalysis , engineering
β‐Graphdiyne (β‐GDY) is a member of 2D graphyne family with zero band gap, and is a promising material with potential applications in energy storage, organic electronics, etc. However, the synthesis of β‐GDY has not been realized yet, and the measurement of its intrinsic properties remains elusive. In this work, β‐GDY‐containing thin film is successfully synthesized on copper foil using modified Glaser–Hay coupling reaction with tetraethynylethene as precursor. The as‐grown carbon film has a smooth surface and is continuous and uniform. Electrical measurements reveal the conductivity of 3.47 × 10 −6 S m −1 and the work function of 5.22 eV. TiO 2 @β‐GDY nanocomposite is then prepared and presented with an enhancement of photocatalytic ability compared to pure TiO 2 .