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Cage‐Like Porous Carbon with Superhigh Activity and Br 2 ‐Complex‐Entrapping Capability for Bromine‐Based Flow Batteries
Author(s) -
Wang Chenhui,
Lai Qinzhi,
Xu Pengcheng,
Zheng Daoyuan,
Li Xianfeng,
Zhang Huamin
Publication year - 2017
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201605815
Subject(s) - bromine , materials science , density functional theory , porosity , faraday efficiency , chemical engineering , carbon fibers , diffusion , nanotechnology , chemistry , computational chemistry , electrochemistry , electrode , composite material , thermodynamics , physics , composite number , engineering , metallurgy
Bromine‐based flow batteries receive wide attention in large‐scale energy storage because of their attractive features, such as high energy density and low cost. However, the Br 2 diffusion and relatively low activity of Br 2 /Br − hinder their further application. Herein, a cage‐like porous carbon (CPC) with specific pore structure combining superhigh activity and Br 2 ‐complex‐entrapping capability is designed and fabricated. According to the results of density functional theory (DFT) calculation, the pore size of the CPC (1.1 nm) is well designed between the size of Br − (4.83 Å), MEP + (9.25 Å), and Br 2 complex (MEPBr 3 12.40 Å), wherein Br − is oxidized to Br 2 , which forms a Br 2 complex with the complexing agent immediately and is then entrapped in the cage via pore size exclusion. In addition, the active sites produced during the carbon dioxide activation process dramatically accelerate the reaction rate of Br 2 /Br − . In this way, combining a high Br 2 ‐entrapping‐capability and high specific surface areas, the CPC shows very impressive performance. The zinc bromine flow battery assembled with the prepared CPC shows a Coulombic efficiency of 98% and an energy efficiency of 81% at the current density of 80 mA cm −2 , which are among the highest values ever reported.