Implementing Metal‐to‐Ligand Charge Transfer in Organic Semiconductor for Improved Visible‐Near‐Infrared Photocatalysis | Zendy

Li Yanrui | Zendy; Wang Zhaowu | Zendy; Xia Tong | Zendy; Ju Huanxin | Zendy; Zhang Ke | Zendy; Long Ran | Zendy; Xu Qian | Zendy; Wang Chengming | Zendy; Song Li | Zendy; Zhu Junfa | Zendy; Jiang Jun | Zendy; Xiong Yujie | Zendy

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Implementing Metal‐to‐Ligand Charge Transfer in Organic Semiconductor for Improved Visible‐Near‐Infrared Photocatalysis

Author(s) -

Li Yanrui,

Wang Zhaowu,

Xia Tong,

Ju Huanxin,

Zhang Ke,

Long Ran,

Xu Qian,

Wang Chengming,

Song Li,

Zhu Junfa,

Jiang Jun,

Xiong Yujie

Publication year - 2016

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.201601960

Subject(s) - photocatalysis , materials science , semiconductor , infrared , ligand (biochemistry) , charge (physics) , visible spectrum , absorption (acoustics) , metal , nanotechnology , photochemistry , optoelectronics , chemistry , organic chemistry , catalysis , optics , physics , biochemistry , receptor , quantum mechanics , metallurgy , composite material

The coordination of organic semiconductors with metal cations can induce metal‐to‐ligand charge transfer, which broadens light absorption to cover the visible–near‐infrared (vis–NIR) spectrum. As a proof‐of‐concept demonstration, the g‐C 3 N 4 ‐based complex exhibits dramatically enhanced photocatalytic H 2 production with excellent durability under vis–NIR irradiation.

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