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Increasing Polymer Solar Cell Fill Factor by Trap‐Filling with F4‐TCNQ at Parts Per Thousand Concentration
Author(s) -
Yan Han,
Manion Joseph G.,
Yuan Mingjian,
García de Arquer F. Pelayo,
McKeown George R.,
Beaupré Serge,
Leclerc Mario,
Sargent Edward H.,
Seferos Dwight S.
Publication year - 2016
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201601553
Subject(s) - trap (plumbing) , materials science , photovoltaic system , polymer , semiconductor , nanotechnology , engineering physics , computer science , optoelectronics , electrical engineering , physics , engineering , composite material , meteorology
Intrinsic traps in organic semiconductors can be eliminated by trap‐filling with F4‐TCNQ. Photovoltaic tests show that devices with F4‐TCNQ at parts per thousand concentration outperform control devices due to an improved fill factor. Further studies confirm the trap‐filling pathway and demonstrate the general nature of this finding.

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