Freezing the Nonclassical Crystal Growth of a Coordination Polymer Using Controlled Dynamic Gradients | Zendy

RubioMartinez Marta | Zendy; Imaz Inhar | Zendy; Domingo Neus | Zendy; Abrishamkar Afshin | Zendy; Mayor Tiago Sotto | Zendy; Rossi René M. | Zendy; Carbonell Carlos | Zendy; deMello Andrew J. | Zendy; Amabilino David B. | Zendy; Maspoch Daniel | Zendy; PuigmartíLuis Josep | Zendy

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Freezing the Nonclassical Crystal Growth of a Coordination Polymer Using Controlled Dynamic Gradients

Author(s) -

RubioMartinez Marta,

Imaz Inhar,

Domingo Neus,

Abrishamkar Afshin,

Mayor Tiago Sotto,

Rossi René M.,

Carbonell Carlos,

deMello Andrew J.,

Amabilino David B.,

Maspoch Daniel,

PuigmartíLuis Josep

Publication year - 2016

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.201506462

Subject(s) - microfluidics , mixing (physics) , diffusion , crystal (programming language) , materials science , reagent , computer science , service (business) , polymer , nanotechnology , chemical physics , thermodynamics , chemistry , physics , business , quantum mechanics , marketing , programming language , composite material

A methodology that can be efficiently used to synthesize, isolate, and study out‐of‐equilibrium crystal structures employing controlled and diffusion‐limited microfluidic environments is demonstrated. Unlike studies conducted with conventional mixing procedures in a flask, it is proven experimentally and with numerical simulations that microfluidic technologies can undoubtedly fine‐tune reaction times and reagents concentration profiles; factors that enable out‐of‐equilibrium crystal forms to be obtained.

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