A Cofacially Stacked Electron‐Deficient Small Molecule with a High Electron Mobility of over 10 cm 2  V −1  s −1  in Air | Zendy

Dou JinHu | Zendy; Zheng YuQing | Zendy; Yao ZeFan | Zendy; Lei Ting | Zendy; Shen Xingxing | Zendy; Luo XuYi | Zendy; Yu ZhiAo | Zendy; Zhang ShiDing | Zendy; Han Guangchao | Zendy; Wang Zhi | Zendy; Yi Yuanping | Zendy; Wang JieYu | Zendy; Pei Jian | Zendy

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A Cofacially Stacked Electron‐Deficient Small Molecule with a High Electron Mobility of over 10 cm 2 V −1 s −1 in Air

Author(s) -

Dou JinHu,

Zheng YuQing,

Yao ZeFan,

Lei Ting,

Shen Xingxing,

Luo XuYi,

Yu ZhiAo,

Zhang ShiDing,

Han Guangchao,

Wang Zhi,

Yi Yuanping,

Wang JieYu,

Pei Jian

Publication year - 2015

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.201503803

Subject(s) - electron , molecule , homo/lumo , charge (physics) , materials science , physics , electron mobility , crystallography , atomic physics , nuclear physics , condensed matter physics , particle physics , chemistry , quantum mechanics

A strong, electron‐deficient small molecule , F 4 ‐BDOPV, has a lowest unoccupied molecular orbital (LUMO) level down to ‐4.44 eV and exhibits cofacial packing in single crystals. These features provide F 4 ‐BDOPV with good ambient stability and large charge‐transfer integrals for electrons, leading to a high electron mobility of up to 12.6 cm 2 V −1 s −1 in air.

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