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Mesoporous Metal–Organic Frameworks with Size‐, Shape‐, and Space‐Distribution‐Controlled Pore Structure
Author(s) -
Zhang Weina,
Liu Yayuan,
Lu Guang,
Wang Yong,
Li Shaozhou,
Cui Chenlong,
Wu Jin,
Xu Zhiling,
Tian Danbi,
Huang Wei,
DuCheneu Joseph S.,
Wei W. David,
Chen Hongyu,
Yang Yanhui,
Huo Fengwei
Publication year - 2015
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201405752
Subject(s) - mesoporous material , materials science , metal organic framework , nanotechnology , porosity , catalysis , metal , nanoparticle , selectivity , chemical engineering , organic chemistry , composite material , adsorption , metallurgy , chemistry , engineering
Mesoporous Metal–organic frameworks (meso‐MOFs) with size‐, shape‐, and space‐distribution‐controlled mesopores are obtained by a facile encapsulation and selective etching strategy of metal nanoparticles. Hierarchical or functionalized meso‐MOFs are achieved by the above strategy. Interestingly, the functional meso‐MOFs display higher catalytic activity originating from the mesopores existing in the MOFs, as well as good selectivity due to protection of the microporous frameworks.