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Soluble Porous Coordination Polymers by Mechanochemistry: From Metal‐Containing Films/Membranes to Active Catalysts for Aerobic Oxidation
Author(s) -
Zhang Pengfei,
Li Haiying,
Veith Gabriel M.,
Dai Sheng
Publication year - 2015
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201403299
Subject(s) - mechanochemistry , polymer , materials science , membrane , porosity , polymerization , catalysis , metal , coordination polymer , transition metal , polymer chemistry , chemical engineering , synthetic membrane , organic chemistry , nanotechnology , chemistry , metallurgy , composite material , biochemistry , engineering
Soluble porous coordination polymers from mechanochemical synthesis are presented through a coordination polymerization between highly contorted, rigid tetraphenol and a broad variety of transition metal ions. These polymers can be easily cast as metal‐containing films or freestanding membranes. Importantly, as‐made coordination polymers are highly active and stable in the aerobic oxidation of allylic CH bonds.