Charge‐Transfer Complex Crystal Based on Extended‐π‐Conjugated Acceptor and Sulfur‐Bridged Annulene: Charge‐Transfer Interaction and Remarkable High Ambipolar Transport Characteristics | Zendy

Qin Yunke | Zendy; Zhang Jing | Zendy; Zheng Xiaoyan | Zendy; Geng Hua | Zendy; Zhao Guangyao | Zendy; Xu Wei | Zendy; Hu Wenping | Zendy; Shuai Zhigang | Zendy; Zhu Daoben | Zendy

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Charge‐Transfer Complex Crystal Based on Extended‐π‐Conjugated Acceptor and Sulfur‐Bridged Annulene: Charge‐Transfer Interaction and Remarkable High Ambipolar Transport Characteristics

Author(s) -

Qin Yunke,

Zhang Jing,

Zheng Xiaoyan,

Geng Hua,

Zhao Guangyao,

Xu Wei,

Hu Wenping,

Shuai Zhigang,

Zhu Daoben

Publication year - 2014

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.201400056

Subject(s) - ambipolar diffusion , annulene , acceptor , tetracyanoquinodimethane , materials science , conjugated system , charge transfer complex , charge (physics) , conductance , crystal (programming language) , photochemistry , electron acceptor , chemical physics , electron , computational chemistry , chemistry , polymer , molecule , organic chemistry , condensed matter physics , physics , quantum mechanics , computer science , composite material , programming language

A single crystal of a novel mixed‐stack donor–acceptor complex formed by a tetracyanoquinodimethane derivative with an extended π‐conjugated system and a sulfur‐bridged annulene displays the highest ambipolar transport behavior among donor–acceptor complexes reported with electron and hole mobilities reaching up to 0.24 and 0.77 cm 2 V −1 s −1 , respectively.

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