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Metal–Organic Frameworks as Cathode Materials for Li–O 2 Batteries
Author(s) -
Wu Doufeng,
Guo Ziyang,
Yin Xinbo,
Pang Qingqing,
Tu Binbin,
Zhang Lijuan,
Wang YongGang,
Li Qiaowei
Publication year - 2014
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201305492
Subject(s) - materials science , metal organic framework , cathode , metal , electrode , chemical engineering , population , nanotechnology , inorganic chemistry , metallurgy , organic chemistry , chemistry , demography , adsorption , sociology , engineering
Metal–organic frameworks (MOFs) with open metal sites enrich the population of O 2 in the pores significantly and assist the Li–O 2 reaction when employed as a cell electrode material. A primary capacity of 9420 mA h g −1 is achieved in a cell with Mn‐MOF‐74; more than four times higher than the value obtained in a cell without an MOF.