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LCST‐Type Phase Behavior Induced by Pillar[5]arene/Ionic Liquid Host–Guest Complexation
Author(s) -
Dong Shengyi,
Zheng Bo,
Yao Yong,
Han Chengyou,
Yuan Jiayin,
Antonietti Markus,
Huang Feihe
Publication year - 2013
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201303652
Subject(s) - lower critical solution temperature , ionic liquid , materials science , pillar , iodide , phase (matter) , phase transition , ionic bonding , chloroform , chemical engineering , polymer chemistry , inorganic chemistry , organic chemistry , chemistry , thermodynamics , ion , catalysis , polymer , composite material , physics , structural engineering , engineering , copolymer
The host−guest complex of dipropoxypillar[5]arene and an ionic liquid 1,3‐dimethylimidazolium iodide is found to exhibit a lower critical solution temperature (LCST)‐type phase transition in chloroform. This LCST‐type phase behavior can be conveniently modulated by experimental parameters and can be easily combined with the ionic liquid for potential application in product and educt separation.