Phase Separation in Garnet Solid Solutions and its Effect on Optical Properties | Zendy

Kaveh Shakiba | Zendy; Tremblay Clément P. | Zendy; Norhashim Nurhakimah | Zendy; Curry Richard J. | Zendy; Cheetham Anthony K. | Zendy

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Phase Separation in Garnet Solid Solutions and its Effect on Optical Properties

Author(s) -

Kaveh Shakiba,

Tremblay Clément P.,

Norhashim Nurhakimah,

Curry Richard J.,

Cheetham Anthony K.

Publication year - 2013

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.201302288

Subject(s) - materials science , erbium , phase (matter) , solid state , doping , solid solution , analytical chemistry (journal) , synchrotron , optics , optoelectronics , chemistry , metallurgy , chromatography , physics , organic chemistry

Phase behavior is studied in erbium‐doped Y 3 Al 5 O 12 (YAG) garnets synthesized by solid‐state reactions. High resolution synchrotron XRD and SEM‐EDX studies reveal phase separation at an erbium content between 8 and 50 at%, depending upon the processing conditions. Similar results are found in closely‐related garnet systems. The phase separation has a striking effect on the optical properties of YAG:Er 3+ .

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