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Solid‐State Reversible Quadratic Nonlinear Optical Molecular Switch with an Exceptionally Large Contrast
Author(s) -
Sun Zhihua,
Luo Junhua,
Zhang Shuquan,
Ji Chengmin,
Zhou Lei,
Li Shenhui,
Deng Feng,
Hong Maochun
Publication year - 2013
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201301685
Subject(s) - contrast (vision) , quadratic equation , nonlinear system , solid state , nonlinear optical , second harmonic generation , materials science , nonlinear optics , motion (physics) , state (computer science) , harmonic , content (measure theory) , computer science , nanotechnology , optics , engineering physics , algorithm , physics , mathematics , quantum mechanics , artificial intelligence , laser , geometry , mathematical analysis
Exceptional nonlinear optical (NLO) switching behavior , including an extremely large contrast (on/off) of ∼35 and high NLO coefficients, is displayed by a solid‐state reversible quadratic NLO switch. The favorable results, induced by very fast molecular motion and anionic ordering, provides impetus for the design of a novel second‐harmonic‐generation switch involving molecular motion.
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