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Spinel/Layered Heterostructured Cathode Material for High‐Capacity and High‐Rate Li‐Ion Batteries
Author(s) -
Wu Feng,
Li Ning,
Su Yuefeng,
Shou Haofang,
Bao Liying,
Yang Wen,
Zhang Linjing,
An Ran,
Chen Shi
Publication year - 2013
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201300598
Subject(s) - spinel , materials science , lithium (medication) , cathode , layer (electronics) , ion , chemical engineering , core (optical fiber) , nanotechnology , composite material , metallurgy , chemistry , engineering , medicine , physics , quantum mechanics , endocrinology
Best of both worlds: A heterostructured material is synthesized that comprises a core of layered lithium‐rich material and an outer layer of nanospinel material. This spinel/layered heterostructured material maximizes the inherent advantages of the 3D Li + insertion/extraction framework of the spinel structure and the high Li + storage capacity of the layered structure. The material exhibits super‐high reversible capacities, outstanding rate capability and excellent cycling ability.

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