Probing the Relation Between Charge Transport and Supramolecular Organization Down to Ångström Resolution in a Benzothiadiazole‐Cyclopentadithiophene Copolymer | Zendy

Niedzialek Dorota | Zendy; Lemaur Vincent | Zendy; Dudenko Dmytro | Zendy; Shu Jie | Zendy; Hansen Michael Ryan | Zendy; Andreasen Jens Wenzel | Zendy; Pisula Wojciech | Zendy; Müllen Klaus | Zendy; Cornil Jérôme | Zendy; Beljonne David | Zendy

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Probing the Relation Between Charge Transport and Supramolecular Organization Down to Ångström Resolution in a Benzothiadiazole‐Cyclopentadithiophene Copolymer

Author(s) -

Niedzialek Dorota,

Lemaur Vincent,

Dudenko Dmytro,

Shu Jie,

Hansen Michael Ryan,

Andreasen Jens Wenzel,

Pisula Wojciech,

Müllen Klaus,

Cornil Jérôme,

Beljonne David

Publication year - 2013

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.201201058

Subject(s) - copolymer , materials science , angstrom , supramolecular chemistry , chemical physics , polymer , charge (physics) , scattering , conjugated system , coupling (piping) , crystallography , polymer chemistry , crystal structure , physics , optics , chemistry , quantum mechanics , composite material , metallurgy

Molecular modeling shows that longitudinal displacement of the backbones by a couple of ångströms has a profound impact on the electronic coupling mediating charge transport in a conjugated copolymer. These changes can be probed by monitoring the calculated X‐ray scattering patterns and NMR chemical shifts as a function of sliding of the polymer chains and comparing them to experiment.

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