Premium
Porous, Fluorescent, Covalent Triazine‐Based Frameworks Via Room‐Temperature and Microwave‐Assisted Synthesis
Author(s) -
Ren Shijie,
Bojdys Michael J.,
Dawson Robert,
Laybourn Andrea,
Khimyak Yaroslav Z.,
Adams Dave J.,
Cooper Andrew I.
Publication year - 2012
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201200751
Subject(s) - triazine , microporous material , materials science , fluorescence , nanotechnology , monomer , covalent bond , scalability , porosity , porous medium , microwave , combinatorial chemistry , polymer chemistry , computer science , organic chemistry , polymer , chemistry , database , physics , telecommunications , composite material , quantum mechanics
Porous, fluorescent, covalent triazine‐based frameworks (CTFs) are obtained in an unprecedentedly mild reaction, opening up a scalable pathway for molecular building blocks previously thought incompatible with this chemistry. Choice of monomers and synthetic conditions determines the optical properties and nano‐scale ordering of these highly microporous materials with BET surface areas exceeding 1100 m 2 g −1 and exceptional CO 2 capacities (up to 4.17 mmol g −1 ).