Highly Stable Porous Polymer Networks with Exceptionally High Gas‐Uptake Capacities | Zendy

Yuan Daqiang | Zendy; Lu Weigang | Zendy; Zhao Dan | Zendy; Zhou HongCai | Zendy

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Highly Stable Porous Polymer Networks with Exceptionally High Gas‐Uptake Capacities

Author(s) -

Yuan Daqiang,

Lu Weigang,

Zhao Dan,

Zhou HongCai

Publication year - 2011

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.201101759

Subject(s) - materials science , polymer , adsorption , porosity , monomer , chemical engineering , methane , hydrogen storage , langmuir , hydrogen , nanotechnology , organic chemistry , composite material , chemistry , alloy , engineering

Highly stable porous polymer networks (PPNs) are synthesized through Yamamoto homocoupling reaction between tetrahedral monomers. Among those polymers, PPN‐4 shows exceptionally high Langmuir surface area of 10063 m 2 g −1 (SA BET : 6461 m 2 g −1 ). It also exhibits ultra‐high hydrogen (158 mg g −1 ), methane (389 mg g −1 ), and carbon dioxide (2121 mg g −1 ) storage capacities. These properties make it a perfect adsorbent for clean energy applications.

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