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Highly Efficient Activation of Molecular Oxygen with Nanoporous Metalloporphyrin Frameworks in Heterogeneous Systems
Author(s) -
Chen Long,
Yang Yong,
Guo Zhaoqi,
Jiang Donglin
Publication year - 2011
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201100974
Subject(s) - materials science , nanoporous , oxygen , metal organic framework , oxygen evolution , nanotechnology , chemical engineering , adsorption , chemistry , organic chemistry , electrochemistry , engineering , electrode
A nanoporous metalloporphyrin framework exhibits high activity in the activation of molecular oxygen and excellent catalytic activity in the aerobic epoxidation of olefins, with high conversion, outstanding selectivity, and broad substrate applicability. The porous framework is reusable and allows large‐scale transformation. These catalytic features are correlated with the structural characteristics of the porous framework and mark a breakthrough for this classic reaction.