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Assembly of Pure Silver‐Tungsten‐Oxide Frameworks from Nanostructured Solution Processable Clusters and Their Evolution into Materials with a Metallic Component
Author(s) -
McGlone Thomas,
Streb Carsten,
Long DeLiang,
Cronin Leroy
Publication year - 2010
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.201001398
Subject(s) - materials science , tungsten , tungsten oxide , oxide , nanotechnology , metal , component (thermodynamics) , chemical engineering , metallurgy , physics , engineering , thermodynamics
Silver‐Tungsten‐Oxide Frameworks: Isomerically pure forms of the unique isopolyoxotungstate system are incorporated into highly connected framework materials using Ag(I) as a linking unit. Thermal treatment of the materials leads to the formation of silver microparticles embedded in a tungsten oxide matrix. This novel synthetic approach promises to create a new class of nanostructured tungsten‐silver‐oxides with exciting physical properties, as well as exemplifies the potential for new frameworks based upon solution processable POM clusters.