Mn II (TCNE) 3/2 (I 3 ) 1/2 –A 3D Network‐Structured Organic‐Based Magnet and Comparison to a 2D Analog | Zendy

Stone Kevin H. | Zendy; Stephens Peter W. | Zendy; McConnell Amber C. | Zendy; Shurdha Endrit | Zendy; Pokhodnya Konstantin I. | Zendy; Miller Joel S. | Zendy

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Mn II (TCNE) 3/2 (I 3 ) 1/2 –A 3D Network‐Structured Organic‐Based Magnet and Comparison to a 2D Analog

Author(s) -

Stone Kevin H.,

Stephens Peter W.,

McConnell Amber C.,

Shurdha Endrit,

Pokhodnya Konstantin I.,

Miller Joel S.

Publication year - 2010

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.200904238

Subject(s) - tetracyanoethylene , ferrimagnetism , antiferromagnetism , magnet , materials science , order (exchange) , crystallography , condensed matter physics , physics , magnetization , chemistry , organic chemistry , magnetic field , quantum mechanics , finance , economics

Mn II (TCNE) 3/2 (I 3 ) 1/2 and Mn II (TCNE)[C 4 (CN) 8 ] 1/2 [tetracyanoethylene (TCNE)] are organic‐based magnets with 3D and 2D extended network structures with vastly different magnetic behavior. They have similar ferrimagnetic coupled layers of Mn II (TCNE) •− with different interlayer couplings, which lead, respectively, to net ferrimagnetic ( T c = 171 K) and antiferromagnetic ( T c = 68 K) order.

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