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Conjugated Microporous Polymers
Author(s) -
Cooper Andrew I.
Publication year - 2009
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.200801971
Subject(s) - conjugated microporous polymer , materials science , microporous material , polymer , conjugated system , amorphous solid , phenylene , nanotechnology , polymer science , organic electronics , organic polymer , copolymer , polymer chemistry , chemical engineering , organic chemistry , composite material , chemistry , physics , transistor , voltage , quantum mechanics , engineering
Conjugated microporous polymers are of great interest because they have potential to combine high surface areas in the dry state with physical properties relevant to organic electronics. A series of recent reports has shown that materials such as poly(aryleneethynylene)s (PAEs), poly(phenyl‐ene butadiynylene)s, poly(phenylene vinylene), poly( p ‐phenylene)s, polysilanes, polyanilines, and polytriazines can be produced as microporous networks with apparent Brunauer–Emmett–Teller surface areas of more than 1000 m 2 g −1 in some cases. Micropore size and surface area can be synthetically fine tuned in amorphous PAE polymers and copolymers, something which was previously thought to be the preserve of ordered crystalline materials such as metal organic frameworks. We review in this Research News article recent progress made by our group and others with particular emphasis on the possible future applications of these materials.