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Exploiting Ionic Coupling in Electronic Devices: Electrolyte‐Gated Organic Field‐Effect Transistors
Author(s) -
Panzer Matthew J.,
Frisbie C. Daniel
Publication year - 2008
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.200800617
Subject(s) - materials science , electrolyte , organic semiconductor , semiconductor , transistor , field effect transistor , ionic bonding , transconductance , nanotechnology , electronics , dielectric , optoelectronics , voltage , electrical engineering , ion , electrode , chemistry , organic chemistry , engineering
Currently there is great interest in using organic semiconductors to develop novel flexible electronic applications. An emerging strategy in organic semiconductor materials research involves development of composite or layered materials in which electronic and ionic conductivity is combined to create enhanced functionality in devices. For example, we and other groups have employed ionic motion to modulate electronic transport in organic field‐effect transistors using solid electrolytes. Not only do these transistors operate at low voltages as a result of greatly enhanced capacitive coupling, but they also display intriguing transport phenomena such as negative differential transconductance. Here, we discuss differences in operation between traditional (e.g., SiO 2 ) and electrolyte‐based dielectrics, suggest further improvements to currently used electrolyte materials, and propose several possibilities for exploiting electrolytes in future applications with both organic and inorganic semiconductors.