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Ammonia Borane Destabilized by Lithium Hydride: An Advanced On‐Board Hydrogen Storage Material
Author(s) -
Kang Xiangdong,
Fang Zhanzhao,
Kong Lingyan,
Cheng Huiming,
Yao Xiangdong,
Lu Gaoqing,
Wang Ping
Publication year - 2008
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.200702958
Subject(s) - ammonia borane , hydrogen storage , lithium hydride , gravimetric analysis , materials science , hydride , lithium (medication) , borane , ammonia , hydrogen , inorganic chemistry , chemical engineering , metallurgy , organic chemistry , ion , chemistry , alloy , catalysis , metal , engineering , ionic bonding , endocrinology , medicine
An advanced hydrogen storage material , with potential for on‐board application, is readily prepared by mechanically milling a 1:1 ammonia borane/lithium hydride (AB/LiH) mixture. The material possesses a H capacity of around 10 wt %, higher than the 2015 DOE gravimetric H capacity target, and can rapidly release over 7 wt % pure H 2 at around 100 °C.
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