A Dynamic Porous Magnet Exhibiting Reversible Guest‐Induced Magnetic Behavior Modulation | Zendy

Cheng X.N. | Zendy; Zhang W.X. | Zendy; Lin Y.Y. | Zendy; Zheng Y.Z. | Zendy; Chen X.M. | Zendy

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A Dynamic Porous Magnet Exhibiting Reversible Guest‐Induced Magnetic Behavior Modulation

Author(s) -

Cheng X.N.,

Zhang W.X.,

Lin Y.Y.,

Zheng Y.Z.,

Chen X.M.

Publication year - 2007

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.200700450

Subject(s) - materials science , adsorption , magnet , single molecule magnet , desorption , trigonal crystal system , porosity , molecule , paramagnetism , crystallography , crystal (programming language) , modulation (music) , nanotechnology , condensed matter physics , crystal structure , chemistry , computer science , organic chemistry , magnetic field , magnetization , composite material , physics , quantum mechanics , acoustics , programming language

A flexible 3D porous magnet [KCo 7 (OH) 3 (ip) 6 (H 2 O) 4 ]·12 H 2 O based on unprecedented trigonal‐prismatic heptanuclear Co II clusters (see figure) is reported to undergo a reversible single‐crystal‐to‐single‐crystal transformation on the desorption/adsorption of guest molecules, accompanied by reversible magnetic property changes. This might be applied for the sensing of coordinative, paramagnetic, small molecules such as O 2 and NO.

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