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Mn Quinonoid Core‐Rh Quinonoid Shell Organometallic Nanospheres as Atom Economical Semiheterogeneous Catalysts in Carbene Transfer Reactions
Author(s) -
Park K. H.,
Jang K.,
Cho Y.,
Chun J.,
Kim H. J.,
Sweigart D. A.,
Son S. U.
Publication year - 2007
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.200700274
Subject(s) - catalysis , carbene , rhodium , shell (structure) , atom (system on chip) , materials science , metal , photochemistry , polymer chemistry , chemistry , organic chemistry , computer science , composite material , embedded system , metallurgy
Mn quinonoid core/Rh quinonoid shell structures are prepared in a step‐by‐step manner and characterized by a variety of instrumental analysis techniques. The core/shell nanospheres show better catalytic activities in carbene transfer reaction of EDA than Rh quinonoid nanospheres, because more catalysts can be prepared using the same amount of rhodium metal.