A Methyl Tricyanoethylenecarboxylate‐Based Room‐Temperature Magnet | Zendy

Pokhodnya K. I. | Zendy; Lefler B. | Zendy; Miller J. S. | Zendy

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A Methyl Tricyanoethylenecarboxylate‐Based Room‐Temperature Magnet

Author(s) -

Pokhodnya K. I.,

Lefler B.,

Miller J. S.

Publication year - 2007

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.200700012

Subject(s) - materials science , magnet , magnetization , molecular magnets , chemical engineering , crystallography , magnetic field , chemistry , physics , quantum mechanics , engineering

A room‐temperature magnet of V[MeTCEC] 2 ·0.6(CH 2 Cl 2 ) composition (MeTCEC = methyl tricyanoethylenecarboxylate) is formed by the reaction of MeTCEC and V(CO) 6 (see figure). Analysis of the magnetization indicates a less disordered structure of V[MeTCEC] 2 ·0.6(CH 2 Cl 2 ) with respect to similarly synthesized V[TCNE] x ·0.34(CH 2 Cl 2 ), presumably because of the much slower reaction of MeTCEC and V(CO) 6 .

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