Premium
Functionalization of Crystalline Colloidal Arrays through Click Chemistry
Author(s) -
Evanoff D. D.,
Hayes S. E.,
Ying Y.,
Shim G. H.,
Lawrence J. R.,
Carroll J. B.,
Roeder R. D.,
Houchins J. M.,
Huebner C. F.,
Foulger S. H.
Publication year - 2007
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.200602901
Subject(s) - click chemistry , surface modification , colloid , cycloaddition , materials science , acrylate , propargyl , 1,3 dipolar cycloaddition , nanotechnology , colloidal particle , copper , polymer chemistry , chemical engineering , combinatorial chemistry , polymer science , organic chemistry , catalysis , polymer , copolymer , chemistry , composite material , engineering , metallurgy
The preparation of well‐defined and regioselectively functionalized ordered colloidal particles through the exploitation of ‘click' transformations is presented; specifically, the copper(I)‐catalyzed Huisgen 1,3‐dipolar cycloaddition between azides and terminal alkynes to form 1,2,3‐triazoles is utilized. This approach is demonstrated through the attachment of 9‐azidomethylanthracene to post‐hydrogel stabilized, ordered poly(propargyl acrylate) colloidal particles.