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Energetic Nitrogen Rich Salts of N , N ‐bis[1(2) H ‐Tetrazol‐5‐yl]amine
Author(s) -
Guo Y.,
Gao H.,
Twamley B.,
Shreeve J. M.
Publication year - 2007
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.200602647
Subject(s) - detonation , amine gas treating , nitrogen , thermal decomposition , materials science , decomposition , molecule , energetic material , melting point , inorganic chemistry , standard enthalpy of formation , chemistry , organic chemistry , explosive material , composite material
Reactions of N , N ‐bis‐[1(2) H ‐tetrazol‐5‐yl]amine (H 2 Bta) with several high nitrogen molecules result in new nitrogen rich energetic salts (see figure). Densities, melting points, decomposition temperatures and elemental analyses are reported. Based on their calculated heats of formation, detonation properties, and thermal and hydrolytic stabilities, these stable compounds hold promise for energetic applications.