A Tetrazolate‐ and Cyano‐Bridged Homometallic Mixed‐Valence Copper( I , II ) Molecular Ferrimagnet | Zendy

Zhang X.M. | Zendy; Zhao Y.F. | Zendy; Zhang X.W. | Zendy; Chen X.M. | Zendy

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A Tetrazolate‐ and Cyano‐Bridged Homometallic Mixed‐Valence Copper( I , II ) Molecular Ferrimagnet

Author(s) -

Zhang X.M.,

Zhao Y.F.,

Zhang X.W.,

Chen X.M.

Publication year - 2007

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.200602410

Subject(s) - ferrimagnetism , tetrazole , antiferromagnetism , valence (chemistry) , materials science , copper , crystallography , acetonitrile , inorganic chemistry , stereochemistry , condensed matter physics , chemistry , organic chemistry , metallurgy , magnetization , physics , quantum mechanics , magnetic field

A solvothermal reaction of a cupric salt and tetrazole in acetonitrile generates a tetrazolate (tta)‐ and cyano‐bridged homometallic mixed‐ valence copper( I , II ) molecular ferrimagnet, [Cu 5 (tta) 6 (CN) 2 ] (see figure), that exhibits a field‐induced transition from a 3D antiferromagnetic state to a ferrimagnetic state at 7.9 K.

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