Premium
A Tetrazolate‐ and Cyano‐Bridged Homometallic Mixed‐Valence Copper( I , II ) Molecular Ferrimagnet
Author(s) -
Zhang X.M.,
Zhao Y.F.,
Zhang X.W.,
Chen X.M.
Publication year - 2007
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.200602410
Subject(s) - ferrimagnetism , tetrazole , antiferromagnetism , valence (chemistry) , materials science , copper , crystallography , acetonitrile , inorganic chemistry , stereochemistry , condensed matter physics , chemistry , organic chemistry , metallurgy , magnetization , physics , quantum mechanics , magnetic field
A solvothermal reaction of a cupric salt and tetrazole in acetonitrile generates a tetrazolate (tta)‐ and cyano‐bridged homometallic mixed‐ valence copper( I , II ) molecular ferrimagnet, [Cu 5 (tta) 6 (CN) 2 ] (see figure), that exhibits a field‐induced transition from a 3D antiferromagnetic state to a ferrimagnetic state at 7.9 K.