A Molecule‐Based Nanoporous Material Showing Tuneable Spin‐Crossover Behavior near Room Temperature | Zendy

Quesada M. | Zendy; de la PeñaO'Shea V. A. | Zendy; Aromí G. | Zendy; Geremia S. | Zendy; Massera C. | Zendy; Roubeau O. | Zendy; Gamez P. | Zendy; Reedijk J. | Zendy

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A Molecule‐Based Nanoporous Material Showing Tuneable Spin‐Crossover Behavior near Room Temperature

Author(s) -

Quesada M.,

de la PeñaO'Shea V. A.,

Aromí G.,

Geremia S.,

Massera C.,

Roubeau O.,

Gamez P.,

Reedijk J.

Publication year - 2007

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.200602284

Subject(s) - bifunctional , spin crossover , nanoporous , materials science , sorption , desorption , solvent , spin (aerodynamics) , molecule , crossover , nanotechnology , condensed matter physics , chemistry , thermodynamics , computer science , adsorption , physics , organic chemistry , catalysis , artificial intelligence

A Fe II ‐based 1D open framework that exhibits room‐temperature spin‐ crossover (SCO) is reported. This material shows a reversible structural, magnetic, and chromatic response to a sorption/desorption process, allowing the tuning of the spin‐transition properties by choosing the appropriate solvent (see figure). This feature represents the first example of a bifunctional material in which host–guest properties directly influence the SCO properties.

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