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Room‐Temperature Aqueous Synthesis of Highly Luminescent BaWO 4 –Polymer Nanohybrids and Their Spontaneous Conversion to Hexagonal WO 3 Nanosheets
Author(s) -
Oaki Y.,
Imai H.
Publication year - 2006
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.200600531
Subject(s) - luminescence , materials science , tungstate , aqueous solution , hexagonal crystal system , polymer , barium , nanotechnology , chemical engineering , crystallography , optoelectronics , organic chemistry , chemistry , engineering , metallurgy , composite material
Enhanced green luminescence is seen in barium tungstate–poly(acrylic acid). This nanohybrid spontaneously forms into h‐WO 3 nanosheets through a bottom‐up approach in aqueous solution around room temperature (see figure). The coordination of electrolytes to the inorganic species can lead to the morphological evolution of crystals and can control the modification of the chemical structure relevant to various optical and magnetic properties.

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