A Two‐Dimensional Porphyrin‐Based Porous Network Featuring Communicating Cavities for the Templated Complexation of Fullerenes | Zendy

Spillmann H. | Zendy; Kiebele A. | Zendy; Stöhr M. | Zendy; Jung T. A. | Zendy; Bonifazi D. | Zendy; Cheng F. | Zendy; Diederich F. | Zendy

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A Two‐Dimensional Porphyrin‐Based Porous Network Featuring Communicating Cavities for the Templated Complexation of Fullerenes

Author(s) -

Spillmann H.,

Kiebele A.,

Stöhr M.,

Jung T. A.,

Bonifazi D.,

Cheng F.,

Diederich F.

Publication year - 2006

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.200501734

Subject(s) - porphyrin , supramolecular chemistry , fullerene , materials science , molecule , cover (algebra) , porosity , template , nanotechnology , surface (topology) , organic molecules , photochemistry , chemistry , organic chemistry , composite material , mechanical engineering , geometry , mathematics , engineering

An unprecedented two‐dimensional porphyrin network featuring dynamic pores capable of hosting fullerenes is realized following a bottom‐up approach at a single‐crystal silver surface. Surface‐ and porphyrin‐driven long‐range interactions between the C 60 guest molecules and porphyrin layer result in the formation of exceptionally large supramolecular hybrid chains and islands (see Figure and Cover).

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