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A Highly Transparent and Luminescent Hybrid Based on the Copolymerization of Surfactant‐Encapsulated Polyoxometalate and Methyl Methacrylate
Author(s) -
Li H.,
Qi W.,
Li W.,
Sun H.,
Bu W.,
Wu L.
Publication year - 2005
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.200500893
Subject(s) - polyoxometalate , copolymer , materials science , polymer , luminescence , methacrylate , pulmonary surfactant , methyl methacrylate , cluster (spacecraft) , fabrication , polymer chemistry , chemical engineering , nanotechnology , organic chemistry , chemistry , computer science , optoelectronics , composite material , catalysis , medicine , alternative medicine , pathology , programming language , engineering
A polyoxometalate‐based hybrid is produced by the copolymerization of a terminal‐unsaturated surfactant‐ encapsulated polyoxometalate and methyl methacrylate. This hybrid exhibits flexible processability, high transparency of the polymer, and high fluorescence of the inorganic cluster (see Figure). The method presented in this paper provides general access to the fabrication of organic–inorganic electrostatic‐complex‐based materials in polymer matrices.