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Energetic Ionic Liquids from Azido Derivatives of 1,2,4‐Triazole
Author(s) -
Xue H.,
Shreeve J. M.
Publication year - 2005
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.200500789
Subject(s) - ionic liquid , propellant , materials science , thermal , ionic bonding , energetic material , triazole , chemical engineering , ion , chemistry , inorganic chemistry , organic chemistry , thermodynamics , catalysis , physics , engineering , explosive material
Energetic ionic liquids with good thermal stabilities, relatively high densities, and high, positive heats of formation are described. Quaternization of azidoalkyl‐substituted 1,2,4‐triazoles with 4,5‐dinitroimidazole or 5‐nitrotetrazole (see Figure) result in room‐temperature liquids that may be useful in energetic materials/propellant applications.