Tetrathiafulvalene [Fe III (C 2 O 4 )Cl 2 ]: An Organic–Inorganic Hybrid Exhibiting Canted Antiferromagnetism | Zendy

Zhang B. | Zendy; Wang Z. | Zendy; Fujiwara H. | Zendy; Kobayashi H. | Zendy; Kurmoo M. | Zendy; Inoue K. | Zendy; Mori T. | Zendy; Gao S. | Zendy; Zhang Y. | Zendy; Zhu D. | Zendy

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Tetrathiafulvalene [Fe III (C 2 O 4 )Cl 2 ]: An Organic–Inorganic Hybrid Exhibiting Canted Antiferromagnetism

Author(s) -

Zhang B.,

Wang Z.,

Fujiwara H.,

Kobayashi H.,

Kurmoo M.,

Inoue K.,

Mori T.,

Gao S.,

Zhang Y.,

Zhu D.

Publication year - 2005

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.200500766

Subject(s) - tetrathiafulvalene , antiferromagnetism , materials science , hybrid material , molecule , ion , polymer , crystallography , inorganic chemistry , condensed matter physics , nanotechnology , organic chemistry , chemistry , physics , composite material

A new organic–inorganic hybrid , (TTF + )Fe III (C 2 O 4 )Cl 2 , displaying canted antiferromagnetism has been prepared and characterized, where the tetrathiafulvalene (TTF) molecules are face‐to‐face dimers and the anion is a one‐dimensional coordination polymer (see Figure). Due to π–d interactions through short S…Cl and S…O contacts a three‐dimensional Néel state is stabilized at the high temperature of 20 K.

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