Single Crystals of ZSM‐5/Silicalite Composites | Zendy

Miyamoto M. | Zendy; Kamei T. | Zendy; Nishiyama N. | Zendy; Egashira Y. | Zendy; Ueyama K. | Zendy

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Single Crystals of ZSM‐5/Silicalite Composites

Author(s) -

Miyamoto M.,

Kamei T.,

Nishiyama N.,

Egashira Y.,

Ueyama K.

Publication year - 2005

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.200500522

Subject(s) - materials science , zsm 5 , catalysis , crystal (programming language) , composite material , toluene , composite number , methanol , alkylation , selectivity , zeolite , chemical engineering , organic chemistry , chemistry , computer science , engineering , programming language

Thin layers of silicalite‐1 were grown on H‐ZSM‐5 crystals. Silicalite‐1 crystals of < 100 nm formed on the ZSM‐5 crystals and grew along the crystal surface (see Figure). The single‐crystal‐like composite catalyst showed excellent para‐selectivity of 99 % in the alkylation of toluene with methanol, and is expected to develop as a new shape‐selective catalyst.

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