The First Example of a Polymer‐Crystal–Organic‐Dye Composite Material: The Clathrate Phase of Syndiotactic Polystyrene with Azulene | Zendy

Uda Y. | Zendy; Kaneko F. | Zendy; Tanigaki N. | Zendy; Kawaguchi T. | Zendy

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The First Example of a Polymer‐Crystal–Organic‐Dye Composite Material: The Clathrate Phase of Syndiotactic Polystyrene with Azulene

Author(s) -

Uda Y.,

Kaneko F.,

Tanigaki N.,

Kawaguchi T.

Publication year - 2005

Publication title -

advanced materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 10.707

H-Index - 527

eISSN - 1521-4095

pISSN - 0935-9648

DOI - 10.1002/adma.200500396

Subject(s) - materials science , polystyrene , azulene , tacticity , polymer , clathrate hydrate , molecule , phase (matter) , chemical engineering , composite number , polymer chemistry , composite material , hydrate , photochemistry , organic chemistry , polymerization , engineering , chemistry

Organic dye molecules have been included in the crystalline regions of syndiotactic polystyrene (sPS) by soaking clathrate or glass films of sPS in an azulene solution containing a plasticizer (see Figure). Highly oriented films, in which the dye molecules are oriented, are easily obtained by applying a similar procedure to an oriented glass sample.

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