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The Combination of Colloid‐Controlled Heterogeneous Nucleation and Polymer‐Controlled Crystallization: Facile Synthesis of Separated, Uniform High‐Aspect‐Ratio Single‐Crystalline BaCrO 4 Nanofibers
Author(s) -
Yu S.H.,
Cölfen H.,
Antonietti M.
Publication year - 2003
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.200390026
Subject(s) - materials science , nucleation , nanofiber , crystallization , colloid , polymer , chemical engineering , copolymer , nanotechnology , aqueous solution , polymer chemistry , composite material , organic chemistry , chemistry , engineering
Uniform, separated BaCrO 4 single‐crystalline nanofibers with high aspect ratio (> 5000, see Figure) can be fabricated at room temperature in aqueous solution using a double hydrophilic block copolymer as structure‐directing agent and introducing colloidal nucleation agents. Such fibers represent a model case for advanced polymer fillers and the exploration of quasi‐1D nanostructures with interesting electrical, optical, or catalytic properties.

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